Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Frady Gouany; Ashraf GHANEM

doi:10.1002/chir.22347

Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Frady Gouany, Ashraf GHANEM

Science

Research output: Contribution to journal › Review article › peer-review

37 Citations (Scopus)

Abstract

In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

Original language	English
Pages (from-to)	692-711
Number of pages	20
Journal	Chirality
Volume	26
Issue number	11
DOIs	https://doi.org/10.1002/chir.22347
Publication status	Published - 2014

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10.1002/chir.22347

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AU - GHANEM, Ashraf

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KW - dirhodium(II)-carboxamidates

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KW - cyclopropanation

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DO - 10.1002/chir.22347

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JO - Chirality

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Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Abstract

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