Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Frady Gouany, Ashraf GHANEM

Research output: Contribution to journalReview article

23 Citations (Scopus)

Abstract

In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

Original languageEnglish
Pages (from-to)692-711
Number of pages20
JournalChirality
Volume26
Issue number11
DOIs
Publication statusPublished - 2014

Cite this

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title = "Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles",
abstract = "In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.",
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Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles. / Gouany, Frady; GHANEM, Ashraf.

In: Chirality, Vol. 26, No. 11, 2014, p. 692-711.

Research output: Contribution to journalReview article

TY - JOUR

T1 - Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

AU - Gouany, Frady

AU - GHANEM, Ashraf

PY - 2014

Y1 - 2014

N2 - In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

AB - In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

KW - dirhodium(II)-carboxylates

KW - dirhodium(II)-carboxamidates

KW - asymmetric

KW - cyclopropanation

KW - cyclopropenation

KW - paddlewheel

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U2 - 10.1002/chir.22347

DO - 10.1002/chir.22347

M3 - Review article

VL - 26

SP - 692

EP - 711

JO - Chirality

JF - Chirality

SN - 0899-0042

IS - 11

ER -