Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Frady Gouany; Ashraf GHANEM

doi:10.1002/chir.22347

Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Frady Gouany
, Ashraf GHANEM

Research output: Contribution to journal › Review article › peer-review

39 Citations (Scopus)

Abstract

In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

Original language	English
Pages (from-to)	692-711
Number of pages	20
Journal	Chirality
Volume	26
Issue number	11
DOIs	https://doi.org/10.1002/chir.22347
Publication status	Published - 2014

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10.1002/chir.22347

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title = "Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles",

abstract = "In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.",

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AU - Gouany, Frady

AU - GHANEM, Ashraf

PY - 2014

Y1 - 2014

N2 - In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

AB - In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed.

KW - dirhodium(II)-carboxylates

KW - dirhodium(II)-carboxamidates

KW - asymmetric

KW - cyclopropanation

KW - cyclopropenation

KW - paddlewheel

UR - https://www.scopus.com/pages/publications/84910137026

U2 - 10.1002/chir.22347

DO - 10.1002/chir.22347

M3 - Review article

SN - 0899-0042

VL - 26

SP - 692

EP - 711

JO - Chirality

JF - Chirality

IS - 11

ER -

Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

Abstract

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