Investigation of Hydrogen Cyanide Generation from the Cyanoacrylate Fuming Process used for Latent Fingermark Detection

To Carlos Fung, Katherine Grimwood, Ronald Shimmon, Xanthe Spindler, Philip Maynard, Christopher Lennard, Claude Roux

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Cyanoacrylate fuming is one of the most common techniques employed for the detection of latent fingermarks on non-porous surfaces such as plastic and glass. The technique is generally applied by exposing items of interest to the vapours generated by heating a suitable quantity of commercial cyanoacrylate adhesive. In this study, the potential for highly toxic hydrogen cyanide (HCN) to be generated from the overheating of cyanoacrylate was investigated. Two commercial cyanoacrylate adhesives and two quantitative methods for the determination of HCN were employed: (i) the sodium picrate method; and (ii) the picrate–resorcinol method. 13C nuclear magnetic resonance (NMR) analysis was used to confirm the presence of cyanide. In addition, the thermal decomposition of cyanoacrylate was studied using simultaneous thermogravimetric and differential thermal analysis (TGA–DTA). It was determined that detectable and quantifiable amounts of HCN were generated from the thermal decomposition of cyanoacrylate monomer and polymer at temperatures as low as 200 °C. Using an optimised picrate–resorcinol method, it was shown that around 10 μg of HCN could be generated from the heating of 1 g of cyanoacrylate monomer at 200 °C. For one of the adhesives tested, this increased to above 100 μg of HCN when 1 g of cyanoacrylate monomer was heated at 280 °C. Recommendations are provided that, if followed, should ensure that the cyanoacrylate fuming process can be safely applied with minimal risk to the operator
Original languageEnglish
Pages (from-to)143-149
Number of pages7
JournalForensic Science International
Volume212
Issue number1-3
DOIs
Publication statusPublished - 2011

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Hydrogen Cyanide
Cyanoacrylates
Adhesives
Heating
Hot Temperature
Differential Thermal Analysis
Poisons
Cyanides
Plastics
Glass
Polymers
Magnetic Resonance Spectroscopy
Sodium

Cite this

Fung, To Carlos ; Grimwood, Katherine ; Shimmon, Ronald ; Spindler, Xanthe ; Maynard, Philip ; Lennard, Christopher ; Roux, Claude. / Investigation of Hydrogen Cyanide Generation from the Cyanoacrylate Fuming Process used for Latent Fingermark Detection. In: Forensic Science International. 2011 ; Vol. 212, No. 1-3. pp. 143-149.
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abstract = "Cyanoacrylate fuming is one of the most common techniques employed for the detection of latent fingermarks on non-porous surfaces such as plastic and glass. The technique is generally applied by exposing items of interest to the vapours generated by heating a suitable quantity of commercial cyanoacrylate adhesive. In this study, the potential for highly toxic hydrogen cyanide (HCN) to be generated from the overheating of cyanoacrylate was investigated. Two commercial cyanoacrylate adhesives and two quantitative methods for the determination of HCN were employed: (i) the sodium picrate method; and (ii) the picrate–resorcinol method. 13C nuclear magnetic resonance (NMR) analysis was used to confirm the presence of cyanide. In addition, the thermal decomposition of cyanoacrylate was studied using simultaneous thermogravimetric and differential thermal analysis (TGA–DTA). It was determined that detectable and quantifiable amounts of HCN were generated from the thermal decomposition of cyanoacrylate monomer and polymer at temperatures as low as 200 °C. Using an optimised picrate–resorcinol method, it was shown that around 10 μg of HCN could be generated from the heating of 1 g of cyanoacrylate monomer at 200 °C. For one of the adhesives tested, this increased to above 100 μg of HCN when 1 g of cyanoacrylate monomer was heated at 280 °C. Recommendations are provided that, if followed, should ensure that the cyanoacrylate fuming process can be safely applied with minimal risk to the operator",
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Investigation of Hydrogen Cyanide Generation from the Cyanoacrylate Fuming Process used for Latent Fingermark Detection. / Fung, To Carlos; Grimwood, Katherine; Shimmon, Ronald; Spindler, Xanthe; Maynard, Philip; Lennard, Christopher; Roux, Claude.

In: Forensic Science International, Vol. 212, No. 1-3, 2011, p. 143-149.

Research output: Contribution to journalArticle

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AU - Fung, To Carlos

AU - Grimwood, Katherine

AU - Shimmon, Ronald

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AU - Maynard, Philip

AU - Lennard, Christopher

AU - Roux, Claude

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AB - Cyanoacrylate fuming is one of the most common techniques employed for the detection of latent fingermarks on non-porous surfaces such as plastic and glass. The technique is generally applied by exposing items of interest to the vapours generated by heating a suitable quantity of commercial cyanoacrylate adhesive. In this study, the potential for highly toxic hydrogen cyanide (HCN) to be generated from the overheating of cyanoacrylate was investigated. Two commercial cyanoacrylate adhesives and two quantitative methods for the determination of HCN were employed: (i) the sodium picrate method; and (ii) the picrate–resorcinol method. 13C nuclear magnetic resonance (NMR) analysis was used to confirm the presence of cyanide. In addition, the thermal decomposition of cyanoacrylate was studied using simultaneous thermogravimetric and differential thermal analysis (TGA–DTA). It was determined that detectable and quantifiable amounts of HCN were generated from the thermal decomposition of cyanoacrylate monomer and polymer at temperatures as low as 200 °C. Using an optimised picrate–resorcinol method, it was shown that around 10 μg of HCN could be generated from the heating of 1 g of cyanoacrylate monomer at 200 °C. For one of the adhesives tested, this increased to above 100 μg of HCN when 1 g of cyanoacrylate monomer was heated at 280 °C. Recommendations are provided that, if followed, should ensure that the cyanoacrylate fuming process can be safely applied with minimal risk to the operator

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