On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights for improved performance of viable whole-cell baeyer-villiger monoxygenase by immobilization

Frady G. Adly

doi:10.3390/catal7110347

On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights for improved performance of viable whole-cell baeyer-villiger monoxygenase by immobilization

Frady G. Adly

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

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Abstract

Modern experiments have offered alternative interpretations on the symmetry of chiral dirhodium(II) carboxylate complexes and its relationship to their level of enantioselectivity. So, this contribution is to provide an insight on how the knowledge around the structure of these catalysts has evolved with a particular emphasis on the impact of this knowledge on enantioselectivity prediction and catalyst design.

Original language	English
Article number	347
Pages (from-to)	1-19
Number of pages	19
Journal	Catalysts
Volume	7
Issue number	11
DOIs	https://doi.org/10.3390/catal7110347
Publication status	Published - 20 Nov 2017

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10.3390/catal7110347Licence: CC BY

ArticleFinal published version, 4.03 MBLicence: CC BY

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keywords = "Asymmetric synthesis, Catalyst design, Chiral catalysis, Dirhodium(II) complexes, Metal-carbene chemistry, Symmetry, dirhodium(II) complexes, metal-carbene chemistry, asymmetric synthesis, symmetry, chiral catalysis, catalyst design",

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AB - Modern experiments have offered alternative interpretations on the symmetry of chiral dirhodium(II) carboxylate complexes and its relationship to their level of enantioselectivity. So, this contribution is to provide an insight on how the knowledge around the structure of these catalysts has evolved with a particular emphasis on the impact of this knowledge on enantioselectivity prediction and catalyst design.

KW - Asymmetric synthesis

KW - Catalyst design

KW - Chiral catalysis

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KW - symmetry

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KW - catalyst design

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On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights for improved performance of viable whole-cell baeyer-villiger monoxygenase by immobilization

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