Preliminary evaluation of a next-generation portable gas chromatograph mass spectrometer (GC-MS) for the on-site analysis of ignitable liquid residues

Alexander VISOTIN, Chris LENNARD

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The detection of ignitable liquid residues (ILRs) at a fire scene can be valuable evidence to indicate if the fire may have been deliberately set. In this study, a commercially-available portable GC-MS, the TRIDION-9, was evaluated for the purpose of on-site fire debris analysis. The instrument, which incorporates a low thermal mass capillary GC and a miniaturised toroidal ion trap mass spectrometer, is designed to use solid-phase microextraction (SPME) as the default sampling method. Four ignitable liquids (petrol, mineral turpentine, kerosene and diesel) and seven substrates (nylon, polypropylene and wool carpet, rubber and foam underlay, untreated pine and polyurethane) were considered. After method optimisation, substrates were burned and spiked with 0.1 µL of ignitable liquid (mineral turpentine, kerosene, diesel fuel, and both neat and weathered unleaded petrol). Sampling was performed via passive headspace SPME adsorption over 3 min immediately followed by analysis using the TRIDION-9 (analysis time <2 min). Field trials were performed on fire debris samples collected from an accelerated structural fire. The data from the portable GC-MS analyses permitted the detection and correct classification of ILRs in the majority of samples analysed. Overall, the TRIDION-9 was found to be well-suited to the field-based analysis of fire debris samples as a preliminary screen to provide rapid presumptive results for fire investigators.
Original languageEnglish
Pages (from-to)203-221
Number of pages19
JournalAustralian Journal of Forensic Sciences
Volume48
Issue number2
DOIs
Publication statusPublished - 2016

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Gases
Kerosene
Turpentine
Solid Phase Microextraction
Minerals
Gasoline
Polyurethanes
Wool
Polypropylenes
Nylons
Rubber
Adsorption
Hot Temperature
Research Personnel
Ions

Cite this

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title = "Preliminary evaluation of a next-generation portable gas chromatograph mass spectrometer (GC-MS) for the on-site analysis of ignitable liquid residues",
abstract = "The detection of ignitable liquid residues (ILRs) at a fire scene can be valuable evidence to indicate if the fire may have been deliberately set. In this study, a commercially-available portable GC-MS, the TRIDION-9, was evaluated for the purpose of on-site fire debris analysis. The instrument, which incorporates a low thermal mass capillary GC and a miniaturised toroidal ion trap mass spectrometer, is designed to use solid-phase microextraction (SPME) as the default sampling method. Four ignitable liquids (petrol, mineral turpentine, kerosene and diesel) and seven substrates (nylon, polypropylene and wool carpet, rubber and foam underlay, untreated pine and polyurethane) were considered. After method optimisation, substrates were burned and spiked with 0.1 µL of ignitable liquid (mineral turpentine, kerosene, diesel fuel, and both neat and weathered unleaded petrol). Sampling was performed via passive headspace SPME adsorption over 3 min immediately followed by analysis using the TRIDION-9 (analysis time <2 min). Field trials were performed on fire debris samples collected from an accelerated structural fire. The data from the portable GC-MS analyses permitted the detection and correct classification of ILRs in the majority of samples analysed. Overall, the TRIDION-9 was found to be well-suited to the field-based analysis of fire debris samples as a preliminary screen to provide rapid presumptive results for fire investigators.",
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Preliminary evaluation of a next-generation portable gas chromatograph mass spectrometer (GC-MS) for the on-site analysis of ignitable liquid residues. / VISOTIN, Alexander; LENNARD, Chris.

In: Australian Journal of Forensic Sciences, Vol. 48, No. 2, 2016, p. 203-221.

Research output: Contribution to journalArticle

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