Total antimony and antimony speciation measurements in environmental matrices by ICP-MS, HPLC-ICPMS and SPME-GC

Bill MAHER, Frank Krikowa, Simon FOSTER, Michael Ellwood, William A. Bennett

Research output: Contribution to conference (non-published works)Poster

Abstract

The measurement of total antimony and antimony species concentrations in biological tissues, bacterial cultures, sediments and natural waters is
described. An emphasis is on the development of novel procedures to concentrate and measure antimony species. Antimony species can be extracted
from marine animal tissues with dilute nitric acid and tetrafluroboric acid and sediments with nitric and hydrochloric acid using microwave heating.
Antimony species can be extracted form sediments with citric acid and separated and quantified by high performance-liquid chromatography-ICPMS.
Volatile antimony species generated by bacteria cultures can concentrated by solid phase micro extraction and measured by desorption, cryogenic
trapping and gas chromatography-mass spectrometry. Antimony species in natural waters (sea and lake waters) can be converted to their hydride
forms, cryogenically trapped and measured using ICPMS. All methods are sensitive enough to measure antimony concentrations at levels commonly
found in the environment
Original languageEnglish
Pages395
Number of pages1
Publication statusPublished - 18 Aug 2018
EventMeeting of The International Mineralogical Association - Melbourne , Melbourne, Australia
Duration: 13 Aug 201817 Aug 2018
Conference number: XXII
https://www.ima2018.com/

Conference

ConferenceMeeting of The International Mineralogical Association
Abbreviated titleIMA2018
CountryAustralia
CityMelbourne
Period13/08/1817/08/18
Internet address

Fingerprint

Antimony
antimony
matrix
Nitric Acid
Sediments
nitric acid
Water
Tissue
sediment
Microwave heating
4-sulfophenylmethallyl ether
Hydrochloric Acid
citric acid
High performance liquid chromatography
hydrochloric acid
Citric Acid
Gas chromatography
lake water
Mass spectrometry
Lakes

Cite this

MAHER, B., Krikowa, F., FOSTER, S., Ellwood, M., & Bennett, W. A. (2018). Total antimony and antimony speciation measurements in environmental matrices by ICP-MS, HPLC-ICPMS and SPME-GC. 395. Poster session presented at Meeting of The International Mineralogical Association , Melbourne, Australia.
MAHER, Bill ; Krikowa, Frank ; FOSTER, Simon ; Ellwood, Michael ; Bennett, William A. / Total antimony and antimony speciation measurements in environmental matrices by ICP-MS, HPLC-ICPMS and SPME-GC. Poster session presented at Meeting of The International Mineralogical Association , Melbourne, Australia.1 p.
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MAHER, B, Krikowa, F, FOSTER, S, Ellwood, M & Bennett, WA 2018, 'Total antimony and antimony speciation measurements in environmental matrices by ICP-MS, HPLC-ICPMS and SPME-GC' Meeting of The International Mineralogical Association , Melbourne, Australia, 13/08/18 - 17/08/18, pp. 395.

Total antimony and antimony speciation measurements in environmental matrices by ICP-MS, HPLC-ICPMS and SPME-GC. / MAHER, Bill; Krikowa, Frank; FOSTER, Simon; Ellwood, Michael; Bennett, William A.

2018. 395 Poster session presented at Meeting of The International Mineralogical Association , Melbourne, Australia.

Research output: Contribution to conference (non-published works)Poster

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AU - Krikowa, Frank

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AU - Bennett, William A.

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N2 - The measurement of total antimony and antimony species concentrations in biological tissues, bacterial cultures, sediments and natural waters isdescribed. An emphasis is on the development of novel procedures to concentrate and measure antimony species. Antimony species can be extractedfrom marine animal tissues with dilute nitric acid and tetrafluroboric acid and sediments with nitric and hydrochloric acid using microwave heating.Antimony species can be extracted form sediments with citric acid and separated and quantified by high performance-liquid chromatography-ICPMS.Volatile antimony species generated by bacteria cultures can concentrated by solid phase micro extraction and measured by desorption, cryogenictrapping and gas chromatography-mass spectrometry. Antimony species in natural waters (sea and lake waters) can be converted to their hydrideforms, cryogenically trapped and measured using ICPMS. All methods are sensitive enough to measure antimony concentrations at levels commonlyfound in the environment

AB - The measurement of total antimony and antimony species concentrations in biological tissues, bacterial cultures, sediments and natural waters isdescribed. An emphasis is on the development of novel procedures to concentrate and measure antimony species. Antimony species can be extractedfrom marine animal tissues with dilute nitric acid and tetrafluroboric acid and sediments with nitric and hydrochloric acid using microwave heating.Antimony species can be extracted form sediments with citric acid and separated and quantified by high performance-liquid chromatography-ICPMS.Volatile antimony species generated by bacteria cultures can concentrated by solid phase micro extraction and measured by desorption, cryogenictrapping and gas chromatography-mass spectrometry. Antimony species in natural waters (sea and lake waters) can be converted to their hydrideforms, cryogenically trapped and measured using ICPMS. All methods are sensitive enough to measure antimony concentrations at levels commonlyfound in the environment

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MAHER B, Krikowa F, FOSTER S, Ellwood M, Bennett WA. Total antimony and antimony speciation measurements in environmental matrices by ICP-MS, HPLC-ICPMS and SPME-GC. 2018. Poster session presented at Meeting of The International Mineralogical Association , Melbourne, Australia.