Visualising substrate-fingermark interactions: Solid-state NMR spectroscopy of amino acid reagent development on cellulose substrates

Xanthe Spindler, Ronald Shimmon, Claude Roux, Chris LENNARD

Research output: Contribution to journalArticle

Abstract

Most spectroscopic studies of the reaction products formed by ninhydrin, 1,2-indanedione-zinc (Ind-Zn) and 1,8-diazafluoren-9-one (DFO) when reacted with amino acids or latent fingermarks on paper substrates are focused on visible absorption or luminescence spectroscopy. In addition, structural elucidation studies are typically limited to solution-based mass spectrometry or liquid nuclear magnetic resonance (NMR) spectroscopy, which does not provide an accurate representation of the fingermark development process on common paper substrates. The research presented in this article demonstrates that solid-state carbon-13 magic angle spinning NMR (13C-MAS-NMR) is a technique that can not only be utilised for structural studies of fingermark enhancement reagents, but is a promising technique for characterising the effect of paper chemistry on fingermark deposition and enhancement. The latter opens up a research area that has been under-explored to date but has the potential to improve our understanding of how fingermark secretions and enhancement reagents interact with paper substrates.
Original languageEnglish
Pages (from-to)8-16
Number of pages9
JournalForensic Science International
Volume250
Issue number10
DOIs
Publication statusPublished - May 2015

Fingerprint

Cellulose
Magnetic Resonance Spectroscopy
Amino Acids
Ninhydrin
Luminescence
Research
Zinc
Mass Spectrometry
Spectrum Analysis
Carbon
1,2-indanedione
1,8-diazafluoren-one

Cite this

Spindler, Xanthe ; Shimmon, Ronald ; Roux, Claude ; LENNARD, Chris. / Visualising substrate-fingermark interactions: Solid-state NMR spectroscopy of amino acid reagent development on cellulose substrates. In: Forensic Science International. 2015 ; Vol. 250, No. 10. pp. 8-16.
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abstract = "Most spectroscopic studies of the reaction products formed by ninhydrin, 1,2-indanedione-zinc (Ind-Zn) and 1,8-diazafluoren-9-one (DFO) when reacted with amino acids or latent fingermarks on paper substrates are focused on visible absorption or luminescence spectroscopy. In addition, structural elucidation studies are typically limited to solution-based mass spectrometry or liquid nuclear magnetic resonance (NMR) spectroscopy, which does not provide an accurate representation of the fingermark development process on common paper substrates. The research presented in this article demonstrates that solid-state carbon-13 magic angle spinning NMR (13C-MAS-NMR) is a technique that can not only be utilised for structural studies of fingermark enhancement reagents, but is a promising technique for characterising the effect of paper chemistry on fingermark deposition and enhancement. The latter opens up a research area that has been under-explored to date but has the potential to improve our understanding of how fingermark secretions and enhancement reagents interact with paper substrates.",
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Visualising substrate-fingermark interactions: Solid-state NMR spectroscopy of amino acid reagent development on cellulose substrates. / Spindler, Xanthe; Shimmon, Ronald; Roux, Claude; LENNARD, Chris.

In: Forensic Science International, Vol. 250, No. 10, 05.2015, p. 8-16.

Research output: Contribution to journalArticle

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AU - Roux, Claude

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